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American Association for the Advancement of Science (AAAS)
Published 2015Staff ViewPublication Date: 2015-10-17Publisher: American Association for the Advancement of Science (AAAS)Print ISSN: 0036-8075Electronic ISSN: 1095-9203Topics: BiologyChemistry and PharmacologyComputer ScienceMedicineNatural Sciences in GeneralPhysicsPublished by: -
2Staff View
ISSN: 1572-9559Keywords: Far-infrared ; submillimeter ; lasers ; vinyl fluoride ; S18O2Source: Springer Online Journal Archives 1860-2000Topics: PhysicsNotes: Abstract A total of nine cw FIR laser lines are reported from two new FIR laser molecules; CH2CHF and S18O2. These two are from a list of twelve candidate molecules that were predicted using a set of selection criteria. The candidate D2 18O was tested, but did not lase. Combining these results with independent studies on other candidates, brings the number of proven laser molecules to 4 out of 5 that were tested. These results confirm the value of the selection criteria as a guideline for predicting new optically pumped FIR laser molecules.Type of Medium: Electronic ResourceURL: -
3Staff View
ISSN: 0449-296XKeywords: Physics ; Polymer and Materials ScienceSource: Wiley InterScience Backfile Collection 1832-2000Topics: Chemistry and PharmacologyNotes: The ultraviolet (λ = 2537 A.) photolysis of a degassed mixed phenyl and methyl polysiloxane liquid is examined in terms of gas and crosslinking yields. Results are compared to the published values obtained by ionizing irradiation of this type of molecule. It is shown that ultraviolet radiation is less efficient by two orders of magnitude in producing decomposition (i.e., gaseous products) than is ionizing radiation. The comparisons for crosslinking efficiencies are less certain, but the yields seem to have much more similar values in this case based on a spectroscopic estimation of crosslinking (i.e., analysis for substituted phenylcyclohexadiene formation). The gas quantum yields were φH2 = 2.6 × 10-5, φCH4 = 0.63 × 10-5, φC2H6 ≈ 0.12 × 10-5, and φC2H2 ≈ 0.06 × 10-5.Additional Material: 9 Ill.Type of Medium: Electronic ResourceURL: