Electron transmission spectroscopy of matrix-isolated N2

Sanche, L. ; Perluzzo, G. ; Michaud, M.

College Park, Md. : American Institute of Physics (AIP)
Published 1985
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
Chemistry and Pharmacology
Notes:
Pseudovibrational levels of the 2Πg state of N−2 are detected via electron transmission through solid xenon films doped with varying concentrations of nitrogen molecules. The resonance is found to produce a significant increase in transmitted current arising from electrons having lost energy to vibrational excitation. The relaxation shifts of the anion in condensed N2 (0.7 eV), argon (0.83 eV), and xenon (1.45 eV) are discussed and compared with calculations made within the framework of the Mott–Littleton and Born models.
Type of Medium:
Electronic Resource
URL: