Chemical effects of satellites on X-ray emission spectra-I. Observation of chemical effects in Cl K"α spectra - kawai, J.; Fujisawa, K.; Gohshi, Y.; Satoko, C. (Elsevier)
Fluorescent K"α X-ray spectra of Cl were observed with a two-crystal spectrometer equipped with Si(111) + Si(111) analyzer crystals. K"α line shapes appeared asymmetrically smeared due to the presence of the shake satellites within the natural width of main lines. Two components, which were assigned to the transitions KM -〉 LM and KM^2 -〉 LM^2 by X"α calculations, were found by numerical deconvolution. The relative intensity of K"α parasites-satellites behind the main lines-was measured for a number of compounds. Bonding effects of KM^n -〉 LM^n satellites-parasites-of chlorine were observed (n = 1, 2). It was found that the more covalent the chlorine compound, the weaker the parasites become except for a few compounds.
http://linkinghub.elsevier.com/retrieve/pii/0584-8547(87)80137-4
Keywords: V; U