Stereo- and regioselective routes to allylic silanes - Negishi, E.-i.; Luo, F.-T.; Rand, C.L. (Elsevier)
The Ni- or Pd-catalyzed reaction of alkenyl iodides with Me"3SiCH"2Mgcl provides various types of allytrimethylsilanes in excellent yields in a highly stereo- and regioselective manner, while the Zr-catalyzed carboalumination of Me"3SiCH"2CCH followed by replacement of Al with carbon groups by known reactions produces allylsilanes represented by 2.
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Keywords: V