A new synthesis of angularly substituted bicyclic systems via an anionic oxy-cope rearrangement - Sathyamoorthi, G.; Thangaraj, K.; Srinivasan, P.C.; Swaminathan, S. (Elsevier)
A general synthesis of trans bicyclic carbinols with an angular methyl substituent using the anionic oxy-Cope rearrangement is reported. The carbinols 13a,l3b,14a, 14b and 15 furnish the bicyclic carbinols 16a, 16b 17a,17b and 18 when treated with potassium hydride in 1,2-dimethoxyeth ane.
http://linkinghub.elsevier.com/retrieve/pii/S0040-4020(01)81524-6
Keywords: V