Haloacrylic acids XI. Photochemical reactions of aliphatic aldehydes with methyl trifluoroacrylate - Shendrik, V.P.; Svoboda, J.; Paleta, O.; Dedek, V. (Elsevier)
Photochemically initiated reactions of aliphatic aldehydes, namely acetaldehyde, propionaldehyde and butyraldehyde, with methyl trifluoroacrylate afforded γ-ketoesters of the type R-CO-CF"2CHF-COOCH"3 in the liquid phase. In the gas phase reaction further products were formed by addition of the aldehyde fragments to the olefinic bond of the methyl trifluoroacrylate.
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