Rotationally resolved threshold photoelectron spectroscopy of H"2O and H"2S - Wang, K.; Lee, M.-T.; McKoy, V.; Wiedmann, R.T.; White, M.G. (Elsevier)
We report both measured and calculated rotationally resolved threshold photoelectron spectra for single-photon coherent VUV ionization of the X ^1A"1 ground state of jet-cooled H"2O and H"2S. Agreement between the calculated and measured spectra is very encouraging. Both the H"2O and H"2S spectra show type a transitions which arise from odd angular momentum components of the photoelectron matrix element and are quite molecular in origin. These type a transitions, however, are much weaker in H"2S due to its more atomiclike character.
http://linkinghub.elsevier.com/retrieve/pii/0009-2614(94)00118-9
Keywords: V; U