Polyisobutylene model elastomers prepared using demonstrably complete end-linking reactions
Sung, P. -H. ; Pan, S. -J. ; Mark, J. E. ; Chang, V. S. C. ; Lackey, J. E. ; Kennedy, J. P.
Springer
Published 1983
Springer
Published 1983
| ISSN: |
1436-2449
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|---|---|
| Source: |
Springer Online Journal Archives 1860-2000
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| Topics: |
Chemistry and Pharmacology
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Physics
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| Notes: |
Summary Linear polyisobutylene (PIB) molecules with either hydroxyl or isopropenyl groups at the chain ends were prepared using cationic polymerizations with bifunctional initiator-chain transfer agents. Extensive spectroscopic analyses confirmed the essentially perfect difunctionality of the two types of polymers. The former polymers were end-linked using an aromatic triisocyanate, and the latter by means of a tetrafunctional silane. The resulting trifunctional and tetrafunctional model PIB networks were found to have absolutely negligible sol fractions, which demonstrates that the end-linking reactions used to prepare them were essentially complete. The networks were studied with regard to their equilibrium stress-strain isotherms in uniaxial extension at 25 °C. The results thus obtained are in satisfactory agreement with theory and yield no evidence whatever for significant elastic contributions from inter-chain entanglements.
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| Type of Medium: |
Electronic Resource
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| URL: |
| _version_ | 1798296233310158848 |
|---|---|
| autor | Sung, P. -H. Pan, S. -J. Mark, J. E. Chang, V. S. C. Lackey, J. E. Kennedy, J. P. |
| autorsonst | Sung, P. -H. Pan, S. -J. Mark, J. E. Chang, V. S. C. Lackey, J. E. Kennedy, J. P. |
| book_url | http://dx.doi.org/10.1007/BF00265316 |
| datenlieferant | nat_lic_papers |
| hauptsatz | hsatz_simple |
| identnr | NLM203095324 |
| issn | 1436-2449 |
| journal_name | Polymer bulletin |
| materialart | 1 |
| notes | Summary Linear polyisobutylene (PIB) molecules with either hydroxyl or isopropenyl groups at the chain ends were prepared using cationic polymerizations with bifunctional initiator-chain transfer agents. Extensive spectroscopic analyses confirmed the essentially perfect difunctionality of the two types of polymers. The former polymers were end-linked using an aromatic triisocyanate, and the latter by means of a tetrafunctional silane. The resulting trifunctional and tetrafunctional model PIB networks were found to have absolutely negligible sol fractions, which demonstrates that the end-linking reactions used to prepare them were essentially complete. The networks were studied with regard to their equilibrium stress-strain isotherms in uniaxial extension at 25 °C. The results thus obtained are in satisfactory agreement with theory and yield no evidence whatever for significant elastic contributions from inter-chain entanglements. |
| package_name | Springer |
| publikationsjahr_anzeige | 1983 |
| publikationsjahr_facette | 1983 |
| publikationsjahr_intervall | 8019:1980-1984 |
| publikationsjahr_sort | 1983 |
| publisher | Springer |
| reference | 9 (1983), S. 375-381 |
| search_space | articles |
| shingle_author_1 | Sung, P. -H. Pan, S. -J. Mark, J. E. Chang, V. S. C. Lackey, J. E. Kennedy, J. P. |
| shingle_author_2 | Sung, P. -H. Pan, S. -J. Mark, J. E. Chang, V. S. C. Lackey, J. E. Kennedy, J. P. |
| shingle_author_3 | Sung, P. -H. Pan, S. -J. Mark, J. E. Chang, V. S. C. Lackey, J. E. Kennedy, J. P. |
| shingle_author_4 | Sung, P. -H. Pan, S. -J. Mark, J. E. Chang, V. S. C. Lackey, J. E. Kennedy, J. P. |
| shingle_catch_all_1 | Sung, P. -H. Pan, S. -J. Mark, J. E. Chang, V. S. C. Lackey, J. E. Kennedy, J. P. Polyisobutylene model elastomers prepared using demonstrably complete end-linking reactions Summary Linear polyisobutylene (PIB) molecules with either hydroxyl or isopropenyl groups at the chain ends were prepared using cationic polymerizations with bifunctional initiator-chain transfer agents. Extensive spectroscopic analyses confirmed the essentially perfect difunctionality of the two types of polymers. The former polymers were end-linked using an aromatic triisocyanate, and the latter by means of a tetrafunctional silane. The resulting trifunctional and tetrafunctional model PIB networks were found to have absolutely negligible sol fractions, which demonstrates that the end-linking reactions used to prepare them were essentially complete. The networks were studied with regard to their equilibrium stress-strain isotherms in uniaxial extension at 25 °C. The results thus obtained are in satisfactory agreement with theory and yield no evidence whatever for significant elastic contributions from inter-chain entanglements. 1436-2449 14362449 Springer |
| shingle_catch_all_2 | Sung, P. -H. Pan, S. -J. Mark, J. E. Chang, V. S. C. Lackey, J. E. Kennedy, J. P. Polyisobutylene model elastomers prepared using demonstrably complete end-linking reactions Summary Linear polyisobutylene (PIB) molecules with either hydroxyl or isopropenyl groups at the chain ends were prepared using cationic polymerizations with bifunctional initiator-chain transfer agents. Extensive spectroscopic analyses confirmed the essentially perfect difunctionality of the two types of polymers. The former polymers were end-linked using an aromatic triisocyanate, and the latter by means of a tetrafunctional silane. The resulting trifunctional and tetrafunctional model PIB networks were found to have absolutely negligible sol fractions, which demonstrates that the end-linking reactions used to prepare them were essentially complete. The networks were studied with regard to their equilibrium stress-strain isotherms in uniaxial extension at 25 °C. The results thus obtained are in satisfactory agreement with theory and yield no evidence whatever for significant elastic contributions from inter-chain entanglements. 1436-2449 14362449 Springer |
| shingle_catch_all_3 | Sung, P. -H. Pan, S. -J. Mark, J. E. Chang, V. S. C. Lackey, J. E. Kennedy, J. P. Polyisobutylene model elastomers prepared using demonstrably complete end-linking reactions Summary Linear polyisobutylene (PIB) molecules with either hydroxyl or isopropenyl groups at the chain ends were prepared using cationic polymerizations with bifunctional initiator-chain transfer agents. Extensive spectroscopic analyses confirmed the essentially perfect difunctionality of the two types of polymers. The former polymers were end-linked using an aromatic triisocyanate, and the latter by means of a tetrafunctional silane. The resulting trifunctional and tetrafunctional model PIB networks were found to have absolutely negligible sol fractions, which demonstrates that the end-linking reactions used to prepare them were essentially complete. The networks were studied with regard to their equilibrium stress-strain isotherms in uniaxial extension at 25 °C. The results thus obtained are in satisfactory agreement with theory and yield no evidence whatever for significant elastic contributions from inter-chain entanglements. 1436-2449 14362449 Springer |
| shingle_catch_all_4 | Sung, P. -H. Pan, S. -J. Mark, J. E. Chang, V. S. C. Lackey, J. E. Kennedy, J. P. Polyisobutylene model elastomers prepared using demonstrably complete end-linking reactions Summary Linear polyisobutylene (PIB) molecules with either hydroxyl or isopropenyl groups at the chain ends were prepared using cationic polymerizations with bifunctional initiator-chain transfer agents. Extensive spectroscopic analyses confirmed the essentially perfect difunctionality of the two types of polymers. The former polymers were end-linked using an aromatic triisocyanate, and the latter by means of a tetrafunctional silane. The resulting trifunctional and tetrafunctional model PIB networks were found to have absolutely negligible sol fractions, which demonstrates that the end-linking reactions used to prepare them were essentially complete. The networks were studied with regard to their equilibrium stress-strain isotherms in uniaxial extension at 25 °C. The results thus obtained are in satisfactory agreement with theory and yield no evidence whatever for significant elastic contributions from inter-chain entanglements. 1436-2449 14362449 Springer |
| shingle_title_1 | Polyisobutylene model elastomers prepared using demonstrably complete end-linking reactions |
| shingle_title_2 | Polyisobutylene model elastomers prepared using demonstrably complete end-linking reactions |
| shingle_title_3 | Polyisobutylene model elastomers prepared using demonstrably complete end-linking reactions |
| shingle_title_4 | Polyisobutylene model elastomers prepared using demonstrably complete end-linking reactions |
| sigel_instance_filter | dkfz geomar wilbert ipn albert fhp |
| source_archive | Springer Online Journal Archives 1860-2000 |
| timestamp | 2024-05-06T09:48:50.163Z |
| titel | Polyisobutylene model elastomers prepared using demonstrably complete end-linking reactions |
| titel_suche | Polyisobutylene model elastomers prepared using demonstrably complete end-linking reactions |
| topic | V ZL U |
| uid | nat_lic_papers_NLM203095324 |