Measurement of crystallization in stretched rubber by rapid-passage NMR
Von Meerwall, E. ; Creel, R. B. ; Griffin, C. F. ; DiCato, E. ; Lin, F. T. ; Lin, F. M.
New York, NY [u.a.] : Wiley-Blackwell
Published 1977
New York, NY [u.a.] : Wiley-Blackwell
Published 1977
| ISSN: |
0021-8995
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|---|---|
| Keywords: |
Chemistry ; Polymer and Materials Science
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| Source: |
Wiley InterScience Backfile Collection 1832-2000
|
| Topics: |
Chemistry and Pharmacology
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Physics
|
| Notes: |
Continuous-wave rapid-passage proton NMR (30 MHz) was performed on lightly crosslinked natural cis-polyisoprene at elongations up to 720%, at temperatures between -100° and 100°C, and after delays of up to several weeks after stretch. A method of separating the spectra into a narrow and a wide component was developed and applied. The results are interpreted in terms of the effects of a glass transition and strain-induced crystallinity and are in general agreement with results by other methods. The degree of crystallinity is found to increase strongly with strain (from zero for unstretched samples to 31% at elongations of 720% at room temperature), to increase with time, reaching equilibirium most rapidly in the most highly strained samples, and to decrease approximately linearly with temperature above about 20°C.
|
| Additional Material: |
5 Ill.
|
| Type of Medium: |
Electronic Resource
|
| URL: |
| _version_ | 1798297807330738176 |
|---|---|
| addmaterial | 5 Ill. |
| autor | Von Meerwall, E. Creel, R. B. Griffin, C. F. DiCato, E. Lin, F. T. Lin, F. M. |
| autorsonst | Von Meerwall, E. Creel, R. B. Griffin, C. F. DiCato, E. Lin, F. T. Lin, F. M. |
| book_url | http://dx.doi.org/10.1002/app.1977.070210605 |
| datenlieferant | nat_lic_papers |
| hauptsatz | hsatz_simple |
| identnr | NLM163628394 |
| iqvoc_descriptor_keyword | iqvoc_00000092:Materials |
| issn | 0021-8995 |
| journal_name | Journal of Applied Polymer Science |
| materialart | 1 |
| notes | Continuous-wave rapid-passage proton NMR (30 MHz) was performed on lightly crosslinked natural cis-polyisoprene at elongations up to 720%, at temperatures between -100° and 100°C, and after delays of up to several weeks after stretch. A method of separating the spectra into a narrow and a wide component was developed and applied. The results are interpreted in terms of the effects of a glass transition and strain-induced crystallinity and are in general agreement with results by other methods. The degree of crystallinity is found to increase strongly with strain (from zero for unstretched samples to 31% at elongations of 720% at room temperature), to increase with time, reaching equilibirium most rapidly in the most highly strained samples, and to decrease approximately linearly with temperature above about 20°C. |
| package_name | Wiley-Blackwell |
| publikationsjahr_anzeige | 1977 |
| publikationsjahr_facette | 1977 |
| publikationsjahr_intervall | 8024:1975-1979 |
| publikationsjahr_sort | 1977 |
| publikationsort | New York, NY [u.a.] |
| publisher | Wiley-Blackwell |
| reference | 21 (1977), S. 1489-1497 |
| schlagwort | Chemistry Polymer and Materials Science |
| search_space | articles |
| shingle_author_1 | Von Meerwall, E. Creel, R. B. Griffin, C. F. DiCato, E. Lin, F. T. Lin, F. M. |
| shingle_author_2 | Von Meerwall, E. Creel, R. B. Griffin, C. F. DiCato, E. Lin, F. T. Lin, F. M. |
| shingle_author_3 | Von Meerwall, E. Creel, R. B. Griffin, C. F. DiCato, E. Lin, F. T. Lin, F. M. |
| shingle_author_4 | Von Meerwall, E. Creel, R. B. Griffin, C. F. DiCato, E. Lin, F. T. Lin, F. M. |
| shingle_catch_all_1 | Von Meerwall, E. Creel, R. B. Griffin, C. F. DiCato, E. Lin, F. T. Lin, F. M. Measurement of crystallization in stretched rubber by rapid-passage NMR Chemistry Polymer and Materials Science Chemistry Polymer and Materials Science Continuous-wave rapid-passage proton NMR (30 MHz) was performed on lightly crosslinked natural cis-polyisoprene at elongations up to 720%, at temperatures between -100° and 100°C, and after delays of up to several weeks after stretch. A method of separating the spectra into a narrow and a wide component was developed and applied. The results are interpreted in terms of the effects of a glass transition and strain-induced crystallinity and are in general agreement with results by other methods. The degree of crystallinity is found to increase strongly with strain (from zero for unstretched samples to 31% at elongations of 720% at room temperature), to increase with time, reaching equilibirium most rapidly in the most highly strained samples, and to decrease approximately linearly with temperature above about 20°C. 0021-8995 00218995 Wiley-Blackwell |
| shingle_catch_all_2 | Von Meerwall, E. Creel, R. B. Griffin, C. F. DiCato, E. Lin, F. T. Lin, F. M. Measurement of crystallization in stretched rubber by rapid-passage NMR Chemistry Polymer and Materials Science Chemistry Polymer and Materials Science Continuous-wave rapid-passage proton NMR (30 MHz) was performed on lightly crosslinked natural cis-polyisoprene at elongations up to 720%, at temperatures between -100° and 100°C, and after delays of up to several weeks after stretch. A method of separating the spectra into a narrow and a wide component was developed and applied. The results are interpreted in terms of the effects of a glass transition and strain-induced crystallinity and are in general agreement with results by other methods. The degree of crystallinity is found to increase strongly with strain (from zero for unstretched samples to 31% at elongations of 720% at room temperature), to increase with time, reaching equilibirium most rapidly in the most highly strained samples, and to decrease approximately linearly with temperature above about 20°C. 0021-8995 00218995 Wiley-Blackwell |
| shingle_catch_all_3 | Von Meerwall, E. Creel, R. B. Griffin, C. F. DiCato, E. Lin, F. T. Lin, F. M. Measurement of crystallization in stretched rubber by rapid-passage NMR Chemistry Polymer and Materials Science Chemistry Polymer and Materials Science Continuous-wave rapid-passage proton NMR (30 MHz) was performed on lightly crosslinked natural cis-polyisoprene at elongations up to 720%, at temperatures between -100° and 100°C, and after delays of up to several weeks after stretch. A method of separating the spectra into a narrow and a wide component was developed and applied. The results are interpreted in terms of the effects of a glass transition and strain-induced crystallinity and are in general agreement with results by other methods. The degree of crystallinity is found to increase strongly with strain (from zero for unstretched samples to 31% at elongations of 720% at room temperature), to increase with time, reaching equilibirium most rapidly in the most highly strained samples, and to decrease approximately linearly with temperature above about 20°C. 0021-8995 00218995 Wiley-Blackwell |
| shingle_catch_all_4 | Von Meerwall, E. Creel, R. B. Griffin, C. F. DiCato, E. Lin, F. T. Lin, F. M. Measurement of crystallization in stretched rubber by rapid-passage NMR Chemistry Polymer and Materials Science Chemistry Polymer and Materials Science Continuous-wave rapid-passage proton NMR (30 MHz) was performed on lightly crosslinked natural cis-polyisoprene at elongations up to 720%, at temperatures between -100° and 100°C, and after delays of up to several weeks after stretch. A method of separating the spectra into a narrow and a wide component was developed and applied. The results are interpreted in terms of the effects of a glass transition and strain-induced crystallinity and are in general agreement with results by other methods. The degree of crystallinity is found to increase strongly with strain (from zero for unstretched samples to 31% at elongations of 720% at room temperature), to increase with time, reaching equilibirium most rapidly in the most highly strained samples, and to decrease approximately linearly with temperature above about 20°C. 0021-8995 00218995 Wiley-Blackwell |
| shingle_title_1 | Measurement of crystallization in stretched rubber by rapid-passage NMR |
| shingle_title_2 | Measurement of crystallization in stretched rubber by rapid-passage NMR |
| shingle_title_3 | Measurement of crystallization in stretched rubber by rapid-passage NMR |
| shingle_title_4 | Measurement of crystallization in stretched rubber by rapid-passage NMR |
| sigel_instance_filter | dkfz geomar wilbert ipn albert |
| source_archive | Wiley InterScience Backfile Collection 1832-2000 |
| timestamp | 2024-05-06T10:13:51.857Z |
| titel | Measurement of crystallization in stretched rubber by rapid-passage NMR |
| titel_suche | Measurement of crystallization in stretched rubber by rapid-passage NMR |
| topic | V ZL U |
| uid | nat_lic_papers_NLM163628394 |